DataVXSmallPaper
journal article·2023-05Open access

Boosting Activity and Selectivity of UiO‐66 through Acidity/Alkalinity Functionalization in Dimethyl Carbonate Catalysis (Small 18/2023)

Han‐Ying Wu, Ye‐Yan Qin, Yi‐Hong Xiao, Jian‐Shan Chen, Runping Ye, Rong Guo, Yuan‐Gen Yao

Small· Volume 19· Issue 18
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Source abstract

Abstract

Pd-NO2-UiO-66 for DMC Catalysis In article number 2208238, Ye-Yan Qin, Yuan-Gen Yao, and co-workers first introduce acidity/alkalinity functionalized metal–organic frameworks (MOFs) into dimethyl carbonate (DMC) catalysis, and the Lewis acidic Pd-NO2-UiO-66 exhibits excellent catalytic behavior. In addition to affecting the interaction of Pd(II) and support, the -NO2 group has a dominant role in the chemisorption of methyl nitrite (MN) and CO for generating DMC.
Source: openalex_inverted_index · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Carbon dioxide utilization in catalysis · Chemical Synthesis and Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Coal to Ethylene Glycol and Its Related Technology Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 P. R. China

State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 P. R. China

School of Chemical Sciences University of Chinese Academy of Sciences Beijing 100049 P. R. China

College of Environmental and Biological Engineering Putian University Putian 351100 P. R. China

School of Chemistry and Chemical Engineering Nanchang University Nanchang 330031 P. R. China

References

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