journal article·2008-06

Reversibility‐Controlled Single Molecular Level Chemical Reaction in a C60 Monolayer via Ionization Induced by Scanning Transmission Microscopy

M. Nakaya, Y. Kuwahara, M. Aono, T. Nakayama

Small· Volume 4· Issue 6
Publisher page

Abstract

10.1002/smll.200701242 The title of the Communication published on page 538 of Issue 5/08 of Small was incorrect; the correct title is “Reversibility-Controlled Single Molecular Level Chemical Reaction in a C60 Monolayer via Ionization Induced by a Scanning Tunneling Microscope”. The caption of Figure 1 was also published incorrectly; the correct caption is: Figure 1. a) Experimental setup and b,c) series of 5-nm×5-nm STM images showing STM-induced polymerization of C60 molecules. All the images are taken at Vs=+1.0 V and It=30 pA. The application of a voltage pulse with Vs=−2.6 V and It=300 pA for 1 s at the point indicated by the cross indicated in (b) forms two C60 dimers, as shown in (c). After depolymerizing these dimers using a voltage pulse with Vs=+3.5 V and It=100 pA, another voltage pulse with Vs=−2.5 V and It=300 pA for 1 s is applied at the same position and a single dimer is formed, as shown in (d).
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Research context

OpenAlex topics: Molecular Junctions and Nanostructures · Force Microscopy Techniques and Applications · Fullerene Chemistry and Applications

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