Enantiomeric Nanostructures: Chiral Nanostructures from Helical Copolymer-Metal Complexes: Tunable Cation-π Interactions and Sergeants and Soldiers Effect (Small 2/2016)
Source abstract
Abstract
Macroscopically chiral nanospheres and nanotubes composed of helical copolymers are described on page 238 by F. Freire, R. Riguera, and co-workers. The presence of a donor co-solvent either activates or deactivates cation–π supramolecular interactions on the chiral monomers of the copolymer, generating either P or M helical senses in the nanostructure through the ‘Sergeants and Soldiers’ effect.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Surface Chemistry and Catalysis · Supramolecular Chemistry and Complexes · Crystallography and molecular interactions
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