journal article·2015-07Open access

Scanning Tunneling Microscopy: Imaging the Predicted Isomerism of Oligo(aniline)s: A Scanning Tunneling Microscopy Study (Small 28/2015)

James O. Thomas, Hugo D. Andrade, Benjamin M. Mills, Neil A. Fox, Heinrich J. K. Hoerber, Charl F. J. Faul

Small· Volume 11· Issue 28

Abstract

Scanning tunneling microscopy and density functional theory calculations are used by H. J. K. Hoerber, C. F. J. Faul, and co-workers on page 3430 to identify and confirm cis/trans isomers of phenyl- and alkyl-capped tetra(aniline). This isomerism is shown to inhibit molecular self-assembly and therefore influence the performance of such molecules, and their parent polymer, poly(aniline), when confined to thin films for device applications.
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Research context

OpenAlex topics: Surface Chemistry and Catalysis · Various Chemistry Research Topics · Porphyrin and Phthalocyanine Chemistry

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Affiliations

Bristol Centre for Functional Nanomaterials, Centre for NSQI University of Bristol Tyndall Avenue BS8 1FD UK

H. H. Wills Physics Laboratory University of Bristol Tyndall Avenue BS8 1TL UK

School of Chemistry University of Bristol Cantock's Close BS8 1TS UK

References

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