Carbene: Solvent‐Induced Facile Synthesis of Cubic‐, Spherical‐, and Honeycomb‐Shape Palladium N‐Heterocyclic Carbene Particles and Catalytic Applications in Cyanosilylation (Small 30/2015)
Source abstract
Abstract
The facile synthesis of palladium N-heterocyclic carbene (NHC) particles with spherical, cubic, and honeycomb morphologies is accomplished by R. Wang and co-workers through adjusting solvent polarity. The structures of the cubic and honeycomb particles are defined as an unprecedented trinuclear palladium-NHC complex. On page 3642, the relationship between the crystal structures and organometallic particles is established. An obvious effect of particle morphologies on catalytic activity and recyclability is observed in heterogeneous cyanosilylation.
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Research context
OpenAlex topics: Catalytic Cross-Coupling Reactions · Asymmetric Hydrogenation and Catalysis · Carbon dioxide utilization in catalysis
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Affiliations
State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 China
University of Chinese Academy of Sciences Beijing 100049 China
References
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