DataVXSmallPaper
journal article·2023-12Open access

Hybrid Heterostructures of a Spin Crossover Coordination Polymer on MoS2: Elucidating the Role of the 2D Substrate (Small 50/2023)

Alejandro Núñez‐López, Ramón Torres‐Cavanillas, Marc Morant‐Giner, Natalia Vassilyeva, Richard Mattana, Sergio Tatay, Philippe Ohresser, Edwige Otero, Emiliano Fonda, Michael Paulus, Víctor Rubio‐Giménez, Alicia Forment‐Aliaga, Eugenio Coronado

Small· Volume 19· Issue 50
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Source abstract

Abstract

Transition Metal Dichalcogenides In article number 2304954, Alicia Forment-Aliaga, Eugenio Coronado, and co-workers present 2D materials as non-innocent substrates for the direct growth of a spin-crossover polymer. By layer-by-layer solution method, crystalline and oriented films of [Fe(py)2{Pt(CN)4}] grow on 1T and 2H MoS2 layers. The charge transfer from 1T MoS2 to iron ions leads to a superior spin-crossover effect in ultrathin films than when 2H-MoS2 is used.
Source: openalex_inverted_index · Quality: baseline

Research context

PolymersNanomaterials

OpenAlex topics: Magnetism in coordination complexes · 2D Materials and Applications · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Instituto de Ciencia Molecular (ICMol) Universitat de València 46980 Catedrático José Beltrán 2 Paterna Spain

Department of Materials University of Oxford OX1 3PH Oxford UK

Department of Chemical and Pharmaceutical Sciences University of Trieste 34127 Via L. Giorgieri 1 Trieste Italy

Unité Mixte de Physique, CNRS, Thales Université Paris‐Saclay 91767 Palaiseau France

Synchrotron SOLEIL L'Orme des Merisiers 91190 Saint Aubin France

Fakultät Physik/DELTA Technische Universität Dortmund 44221 Dortmund Germany

Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS) Katholieke Universiteit Leuven Celestijnenlaan 200F Leuven 3001 Belgium

References

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