journal article·2023-11Open access

Tuning the Porosity of Dextran Microgels with Supramacromolecular Nanogels as Soft Sacrificial Templates (Small 45/2023)

Selin Bulut, Se‐Hyeong Jung, Thomas Bissing, Florian Schmitt, Michelle Bund, Susanne Braun, Andrij Pich

Small· Volume 19· Issue 45

Abstract

Bio-Based Microgels In article number 2303783, Andrij Pich and co-workers report a versatile method to tune the porosity of dextran-based microgels. The size of mesopores (≤50 nm) in diameter is regulated by the variation of the polymer concentration. For the generation of the macropores (300 to 690 nm), pH-degradable supramacromolecular nanogels are used as a sacrificial colloidal template. Different sizes of the sacrificial nanogels are synthesized via precipitation polymerization and subsequently embedded in the polymer matrix of the microgels via droplet-based microfluidics. The authors demonstrate that uniform voids in the macropore range can be realized by degrading the incorporated sacrificial nanogels.
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Research context

OpenAlex topics: Innovative Microfluidic and Catalytic Techniques Innovation · Hydrogels: synthesis, properties, applications · 3D Printing in Biomedical Research

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Affiliations

DWI – Leibniz Institute for Interactive Materials e. V. RWTH Aachen University Forckenbeckstr. 50 52074 Aachen Germany

Functional and Interactive Polymers Institute of Technical and Macromolecular Chemistry (ITMC) RWTH Aachen University Worringerweg 2 52074 Aachen Germany

Laboratory for Soft Materials and Interfaces Department of Materials, ETH Zürich Vladimir‐Prelog‐Weg 1–5/10 Zürich 8093 Switzerland

Aachen Maastricht Institute for Biobased Materials (AMIBM) Maastricht University Brightlands Chemelot Campus Urmonderbaan 22 Geleen 6167 RD Netherlands

References

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