Nanoparticles: Well Shaped Mn₃O₄ Nano‐octahedra with Anomalous Magnetic Behavior and Enhanced Photodecomposition Properties (Small 4/2011)

Abstract Very uniform and well shaped Mn₃O₄ nano‐octahedra are synthesized using a simple hydrothermal method under the help of polyethylene glycol (PEG200) as a reductant and shape‐directing agent. The nano‐octahedra formation mechanism is monitored. The shape and crystal orientation of the nanoparticles is reconstructed by scanning electron microscopy and electron tomography, which reveals that the nano‐octahedra only selectively expose {101} facets at the external surfaces. The magnetic testing demonstrates that the Mn₃O₄ nano‐octahedra exhibit anomalous magnetic properties: the Mn₃O₄ nano‐octahedra around 150 nm show a similar Curie temperature and blocking temperature to Mn₃O₄ nanoparticles with 10 nm size because of the vertical axis of [001] plane and the exposed {101} facets. With these Mn₃O₄ nano‐octahedra as a catalyst, the photodecomposition of rhodamine B is evaluated and it is found that the photodecomposition activity of Mn₃O₄ nano‐octahedra is much superior to that of commercial Mn₃O₄ powders. The anomalous magnetic properties and high superior photodecomposition activity of well shaped Mn₃O₄ nano‐octahedra should be related to the special shape of the nanoparticles and the abundantly exposed {101} facets at the external surfaces. Therefore, the shape preference can largely broaden the application of the Mn₃O₄ nano‐octahedra.