Catalytic Hydrogenation: Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (CoxRh100−x@SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates (Small 5/2021)
Source abstract
Abstract
In article number 2006683, Alexis Bordet, Walter Leitner, and co-workers present bimetallic cobalt-rhodium nanoparticles of precisely controlled Co:Rh ratios synthesized on imidazolium-based supported ionic liquid phases (CoxRh100−x@SILP) following an organometallic approach. The resulting materials are characterized in detail, and their hydrogenation performances are investigated using multifunctional aromatic substrates as chemical probes. The Co:Rh ratio of the nanoparticles has a critical and synergistic influence on the activity and selectivity controlling in particular the ring hydrogenation of the aromatic moiety.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Asymmetric Hydrogenation and Catalysis · Innovative Microfluidic and Catalytic Techniques Innovation
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Max Planck Institute for Chemical Energy Conversion Stiftstrasse 34–36 Mülheim an der Ruhr 45470 Germany
Institut für Technische und Makromolekulare Chemie RWTH Aachen University Worringerweg 2 Aachen 52074 Germany
Laboratoire de Physique et Chimie des Nano‐Objets Université de Toulouse INSA UPS LPCNO CNRS‐UMR5215 135 Avenue de Rangueil Toulouse 31077 France
References
Reference metadata was not supplied for this record.