journal article·2024-10Open access

Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu 2 (tebpz) MOF (Small 42/2024)

Sebastiano Merchiori, Andrea Le Donne, Ribhu Bhatia, Marta Alvelli, Jiang‐Jing Yu, Xu‐Dong Wu, Mian Li, Dan Li, Lukasz Scheller, Alexander R. Lowe, Monika Geppert‐Rybczynska, Benjamin A. Trump, Andrey A. Yakovenko, Mirosław Chorążewski, Paweł Zajdel, Yaroslav Grosu, Simone Meloni

Small· Volume 20· Issue 42

Abstract

Intrusion Pressure The high vapor confined within the hydrophobic Cu2(tebpz) metal–organic framework led to a counterintuitive trend of the intrusion pressure with temperature, compared to naïve interpretations of the classical Young-Laplace law. This is due to a peculiar combination of the geometrical and chemical characteristics of the porous medium, favoring the formation of a dense vapor inside the material. More in article number 2402173, Andrea Le Donne, Pawel Zajdel, Yaroslav Grosu, and co-workers. Image design by Veronica Vitali from University of Ferrara.
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Research context

OpenAlex topics: Gas Dynamics and Kinetic Theory · Ionosphere and magnetosphere dynamics · Metal-Organic Frameworks: Synthesis and Applications

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Affiliations

Department of Chemical Pharmaceutical and Agricultural Sciences University of Ferrara Ferrara 44121 Italy

College of Chemistry and Chemical Engineering Chemistry and Chemical Engineering Guangdong Laboratory Shantou University Guangdong 515063 China

College of Chemistry and Materials Science Jinan University Guangzhou 510632 China

Institute of Physics University of Silesia Chorzów 41‐500 Poland

Institute of Chemistry University of Silesia Szkolna 9 Katowice 40‐006 Poland

NIST Center for Neutron Research National Institute of Standards and Technology Gaithersburg MD 20899 USA

X‐Ray Science Division Advanced Photon Source Argonne National Laboratory Argonne IL 60439 USA

Centre for Cooperative Research on Alternative Energies (CIC energiGUNE) Basque Research and Technology Alliance (BRTA) Vitoria‐Gasteiz 01510 Spain

References

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