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journal article·2020-04Open access

Oxidative Desulfurization: Confined Heteropoly Blues in Defected Zr‐MOF (Bottle Around Ship) for High‐Efficiency Oxidative Desulfurization (Small 14/2020)

Xue Chang, Xian‐Feng Yang, Yang Qiao, Shuo Wang, Ming‐Hui Zhang, Jun Xu, Dan‐Hong Wang, Xian‐He Bu

Small· Volume 16· Issue 14
Publisher pageOpen full text
Source abstract

Abstract

In article number 1906432, Dan-Hong Wang, Xian-He Bu, and co-workers present a novel design strategy aiming to form heteropoly blues confined in defected Zr-metal–organic framework (MOF), which can expose more unsaturated metal sites to promote the catalytic activity by adding thiourea. Moreover, 1-butyl 3-methyl imidazolium phosphomolybdate blues are also confined in Zr-MOF to obtain higher oxidative desulfurization activity owing to the affinity between electron-rich thiophene-based compounds and electrophilic imidazolium compounds.
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Research context

Catalysis & surfaces

OpenAlex topics: Chemical Synthesis and Reactions · Metal-Organic Frameworks: Synthesis and Applications · Catalysis and Hydrodesulfurization Studies

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Affiliations

TKL of Metal and Molecule Based Material Chemistry National Institute for Advanced Materials School of Materials Science and Engineering Nankai University Tianjin 300350 P. R. China

Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) College of Chemistry Nankai University Tianjin 300071 P. R. China

Center for Rare Earth and Inorganic Functional Materials Tianjin Key Lab for Rare Earth Materials and Applications School of Materials Science and Engineering and National Institute for Advanced Materials Nankai University Tianjin 300350 P. R. China

References

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