1D Metal Mediated Hydrogen Bonded Rods with Rich Phenyl Groups for Highly Efficient Oil Removal
Source abstract
Abstract
Abstract In this work, a novel 1D metal‐mediated hydrogen‐bonded framework with rich phenyl groups is first synthesized employing Co2+ and dibenzoylmethane (DBM) as precursors, which are named HOF‐Co‐DBM and exhibit exceptional thermal stability, excellent chemical durability, and super hydrophobicity. These distinctive properties can be attributed to the high density, robust Co─O coordination bonds, and the presence of strong hydrogen bonds (O─H─O─C) characterized by short bond distances, which contribute to its close‐packed structure. Additionally, the benzene rings flanking the framework further enhance its hydrophobicity. The HOF‐Co‐DBM is subsequently integrated into a polyurethane (PU) sponge, resulting in exceptional oil removal performance. This study demonstrates the potential for preparing ultra‐stable and superhydrophobic hydrogen‐bonded organic framework materials with a wide range of applications.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Enhanced Oil Recovery Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China
Department of Chemistry College of Sciences Northeastern University Shenyang 110819 China
Key Laboratory of Rare Earths Ganjiang Innovation Academy Chinese Academy of Sciences Ganzhou 341000 China
Fujian Key Laboratory of Polymer Materials College of Chemistry and Materials Science Fujian Normal University Fuzhou 350007 China
Funding
National Natural Science Foundation of China · Youth Innovation Promotion Association of the Chinese Academy of Sciences
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