Modulation on the Iron Centers by Selective Synthesis of Organic Ligands with Stereo‐Specific Conformations
Source abstract
Abstract
Abstract Advanced fabrication of surface metal–organic complexes with specific coordination configuration and metal centers will facilitate to exploit novel nanomaterials with attractive electronic/magnetic properties. The precise on‐surface synthesis provides an appealing strategy for in situ construction of complex organic ligands from simple precursors autonomously. In this paper, distinct organic ligands with stereo‐specific conformation are separately synthesized through the well‐known dehalogenative coupling. More interestingly, the exo‐bent ligands promote the mono‐iron chelated complexes with the Fe center significantly decoupled from the surface and of high spin, while the endo‐bent ligands lead to bi‐iron chelated ones instead with ferromagnetic properties.
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Research context
OpenAlex topics: Surface Chemistry and Catalysis · Nanomaterials for catalytic reactions · Molecular Junctions and Nanostructures
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Herbert Gleiter Institute of Nanoscience School of Materials Science and Engineering Nanjing University of Science and Technology Nanjing 210094 P. R. China
Department of Applied Physics and Institution of Energy and Microstructure Nanjing University of Science and Technology Nanjing 210094 P. R. China
Physikalisches Institute Westfälische Wilhelms‐Universität Münster 48149 Münster Germany
Center for Nanotechnology (CeNTech) Heisenbergstrasse 11 48149 Münster Germany
Funding
National Natural Science Foundation of China · Fundamental Research Funds for the Central Universities
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