journal article·2016-05Open access

Metal‐Organic Frameworks: Bimetallic Metal‐Organic Frameworks: Probing the Lewis Acid Site for CO2 Conversion (Small 17/2016)

Ruyi Zou, Pei‐Zhou Li, Yong‐Fei Zeng, Jia Liu, Ruo Zhao, Hui Duan, Zhong Luo, Jin‐Gui Wang, Ruqiang Zou, Yanli Zhao

Small· Volume 12· Issue 17

Abstract

On page 2334, R. Q. Zou, Y. L. Zhao, and co-workers present a porous metal-organic framework (MOF) that serves as a platform for studying the metal exchange effect on both CO2 adsorption and catalytic fixation. The effect is demonstrated by catalytic CO2 cycloaddition with propylene oxide to produce propylene carbonate. Molecular dynamic simulations are carried out to further confirm the catalytic performance of these MOFs on chemical fixation of CO2 to carbonates. This research sheds light on how metal exchange could influence the intrinsic properties of MOFs.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Machine Learning in Materials Science · Carbon Dioxide Capture Technologies

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Affiliations

Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University 21 Nanyang Link Singapore 637371 Singapore

College of Chemistry and Molecular Engineering Zhengzhou University Zhengzhou Henan 450001 China

Singapore Peking University Research Centre for a Sustainable Low‐Carbon Future 1 Create Way Singapore 138602 Singapore

Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials Department of Materials Science and Engineering College of Engineering Peking University Beijing 100871 China

School of Materials Science and Engineering Nanyang Technological University 50 Nanyang Avenue Singapore 639798 Singapore

References

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