Prevention of Sn and Pb Crystallization in a Confined Nanospace
Source abstract
Abstract
Sn, Pb, Ag, and Au are encapsulated within carbon nanotubes (CNTs) by capillary action. From high-resolution transmission electron microscopy imaging of the obtained materials, it is found that although Ag and Au crystallize within CNTs, Sn and Pb are in a pseudoliquid phase. The results suggest that a confined nanospace prevents crystal growth of metals having a low melting point. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: nanoparticles nucleation surface interactions · Crystallization and Solubility Studies · Ion-surface interactions and analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (17)
Show source-provided references
1. 10.1038/361333a010.1038/361333a0 ↗
2. 10.1039/b200537a10.1039/b200537a ↗
3. 10.1021/cm990546o10.1021/cm990546o ↗
4. 10.1021/nl070313t10.1021/nl070313t ↗
5. 10.1007/s12274-008-8013-810.1007/s12274-008-8013-8 ↗
6. 10.1002/adma.20090434610.1002/adma.200904346 ↗
7. Traces of oxygen can be found in the EDX spectra and are assumed to originate from impurities. The existence of SnOxand PbOxis unlikely because the incorporation of molten Sn and Pb within CNTs is performed under high vacuum (≈10−4Pa). In particular the standard free energy of PbO2is considerably higher than that of CO2from room temperature to the reaction temperature of 723K. Therefore we can reasonably assume that the encapsulated materials are pure metal rather than oxidized.
8. 10.1103/PhysRevLett.56.61610.1103/PhysRevLett.56.616 ↗
9. 10.1126/science.112459410.1126/science.1124594 ↗
10. Sudo H. · 1972
11. 10.2355/tetsutohagane1955.63.9_156410.2355/tetsutohagane1955.63.9_1564 ↗
12. 10.1080/1478643720822930310.1080/14786437208229303 ↗
13. 10.1063/1.169943510.1063/1.1699435 ↗
14. 10.1016/0040-6090(86)90422-010.1016/0040-6090(86)90422-0 ↗
15. 10.1140/epjd/e2005-00319-x10.1140/epjd/e2005-00319-x ↗
16. 10.1103/PhysRevA.13.228710.1103/PhysRevA.13.2287 ↗
17. 10.1166/jnn.2008.SW2310.1166/jnn.2008.SW23 ↗