journal article·2026-05

Anode‐Free Lithium Batteries Enabled by Solid Polymer Electrolytes

Yuezheng Liu, Jingfu Shi, Yifan Wang, Shengnan He, Hongge Pan, Zhijun Wu, Yong Wu, Yingying Lu

Small· Volume 22· Issue 28
Publisher page

Abstract

ABSTRACT Anode‐free solid polymer electrolytes (AF‐SPEs) offer a compelling route to maximize cell‐level energy density while improving safety, cost, and manufacturability by replacing the anode with a bare current collector and leveraging ultrathin, low‐density polymer membranes. This review explores key design strategies for optimizing SPE performance in anode‐free lithium metal batteries (AFLMBs), focusing on their role in regulating lithium deposition, enhancing interfacial stability, and improving electro‐chemo‐mechanical robustness. It also examines the fundamental strategies for enhancing the performance of AF‐SPEs, including polymer chemistry, interfacial engineering, and full‐cell lithium inventory management. The review provides insights into the potential of AF‐SPEs to maximize the cell‐level energy density as well as to drive the commercialization of high‐performance, anode‐free solid‐state batteries.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering Zhejiang University Hangzhou China

Institute of Science and Technology for New Energy Xi'an Technological University Xi'an China

Department of Energy and Environmental Materials Suzhou National Laboratory Suzhou China

ZJU‐Hangzhou Global Scientific and Technological Innovation Center Zhejiang University Hangzhou China

Funding

National Natural Science Foundation of China

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