Nanoscale Evidence of Junction‐Limited Transport in Ti ₃ C ₂ T _x MXene

ABSTRACT Understanding charge transport in networks of 2D crystals is essential for developing reliable applications such as chemiresistors or electromagnetic shields. For this purpose, intra‐ and inter‐flake contributions to the network resistance must be disentangled. MXenes such as Ti ₃ C ₂ T _x , are prime examples of 2D crystals often employed as thin networks of interconnected flakes for functional devices. While a significant number of studies focused on transport in individual MXene flakes, inter‐flake transport remains scarcely explored. Here, we demonstrate that charge transport in multi‐flake conductive paths of Ti ₃ C ₂ T _x is dominated by interflake junctions and provide quantitative estimates of junction resistances. Scanning probe measurements reveal that in a MXene multi‐flake conductive path, individual flakes behave as isopotential domains, since the voltage drop is localized precisely at inter‐flake junctions. The chemiresistive response to humidity is further investigated at the single flake, multi‐flake and flake network scale, evidencing the crucial impact of junctions on sensing kinetics. These findings underline the dominant role of inter‐flake junctions in MXene charge transport and sensing capabilities.