journal article·2026-01

Highly Conductive and Supertough PVDF‐Based Electrolytes with Self‐Defective Fillers for Solid‐State Lithium Metal Batteries

Kaibo Fan, Biao Wang, Jie Chen, Kai Cao, Chenyang Zhang, Jun Chen, Yong Zhao, Jiren Yuan, Zhengguang Hu, Li Wang

Small· Volume 22· Issue 5
Publisher page

Abstract

Abstract Advanced PVDF‐based electrolytes with ceramic‐like ion migration behavior, near‐separator‐level toughness, and excellent oxidation resistance are critical for the practical implementation of solid‐state lithium‐metal batteries (SSLMBs). However, the superior ion conductivity, robust mechanical property, and wide electrochemical stability usually cannot be achieved simultaneously. Herein, the self‐defective silicon (Si) fillers with silicon/silicon oxide (Si/SiO x ,06200 h), and the LFP||Li batteries exhibit remarkable fast‐charging behavior at 10 C with the capacity retention of 82.29%.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Thermal Expansion and Ionic Conductivity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University Nanchang 330031 China

Chongqing Institute of New Energy Storage Materials and Equipment Chongqing 401120 China

Institute of Zhejiang University‐Quzhou Zheda Road 99 Quzhou 324000 China

Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology College of Chemical and Biological Engineering Zhejiang University Hangzhou 310027 China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Jiangxi Province

References (46)

Show source-provided references
1. 10.1038/nenergy.2016.14110.1038/nenergy.2016.141 ↗
2. 10.1038/nchem.208510.1038/nchem.2085 ↗
3. 10.1021/acs.chemrev.9b0042710.1021/acs.chemrev.9b00427 ↗
4. 10.1016/j.enchem.2021.10005810.1016/j.enchem.2021.100058 ↗
5. 10.1021/acsenergylett.9b0240110.1021/acsenergylett.9b02401 ↗
6. 10.1016/j.ensm.2022.06.02510.1016/j.ensm.2022.06.025 ↗
7. 10.1016/j.ensm.2016.07.00310.1016/j.ensm.2016.07.003 ↗
8. 10.1002/adma.20190202910.1002/adma.201902029 ↗
9. 10.1002/aenm.20180070310.1002/aenm.201800703 ↗
10. 10.1016/j.chempr.2019.05.00910.1016/j.chempr.2019.05.009 ↗
11. 10.1002/adma.20230850710.1002/adma.202308507 ↗
12. 10.1002/adfm.20221443210.1002/adfm.202214432 ↗
13. 10.1016/j.ensm.2022.06.04010.1016/j.ensm.2022.06.040 ↗
14. 10.1002/smtd.20210026210.1002/smtd.202100262 ↗
15. 10.1007/s12274-023-5658-210.1007/s12274-023-5658-2 ↗
16. 10.1021/jacs.3c0748210.1021/jacs.3c07482 ↗
17. 10.1002/adma.20240154910.1002/adma.202401549 ↗
18. 10.1002/adfm.20240913410.1002/adfm.202409134 ↗
19. 10.1002/adfm.20201026110.1002/adfm.202010261 ↗
20. 10.1002/aenm.20240278210.1002/aenm.202402782 ↗
21. 10.1002/adfm.20230472710.1002/adfm.202304727 ↗
22. 10.1002/ange.20210153710.1002/ange.202101537 ↗
23. 10.1039/D2EE01053D10.1039/D2EE01053D ↗
24. 10.1038/s41467-022-29118-610.1038/s41467-022-29118-6 ↗
25. 10.1002/advs.20220391610.1002/advs.202203916 ↗
26. 10.1002/anie.20211091710.1002/anie.202110917 ↗
27. 10.1002/aenm.20230271110.1002/aenm.202302711 ↗
28. 10.1038/s41563-023-01792-x10.1038/s41563-023-01792-x ↗
29. 10.1002/ange.20240142810.1002/ange.202401428 ↗
30. 10.1016/j.cej.2023.14641410.1016/j.cej.2023.146414 ↗
31. 10.1021/acsnano.2c0692410.1021/acsnano.2c06924 ↗
32. 10.1016/j.jpowsour.2012.08.06010.1016/j.jpowsour.2012.08.060 ↗
33. 10.1021/acsaem.2c0190310.1021/acsaem.2c01903 ↗
34. 10.1002/adma.20231119510.1002/adma.202311195 ↗
35. Yang K. · J. Am. Chem. Soc. · 2024 · 146
36. 10.1039/D4SC05464D10.1039/D4SC05464D ↗
37. 10.1021/jacs.4c0173510.1021/jacs.4c01735 ↗
38. 10.1002/ange.20231487610.1002/ange.202314876 ↗
39. 10.1149/1945-7111/acf48210.1149/1945-7111/acf482 ↗
40. 10.1002/adfm.20242214710.1002/adfm.202422147 ↗
41. 10.1002/adfm.20250048110.1002/adfm.202500481 ↗
42. 10.1016/j.jechem.2024.11.05010.1016/j.jechem.2024.11.050 ↗
43. 10.1002/adma.20200274110.1002/adma.202002741 ↗
44. 10.1002/aenm.20210004610.1002/aenm.202100046 ↗
45. 10.1002/adfm.20230704510.1002/adfm.202307045 ↗
46. 10.1038/s41467-023-41808-310.1038/s41467-023-41808-3 ↗