DataVXSmallPaper
journal article·2024-07

Designable Synthesis of Layered Silicates and Tunable Interlayer Expanded to Zeolites

Ya Wang, Rusi Peng, Weihao Sun, Shiqing Li, Shitao Wu, Hao Xu, Jingang Jiang, Shifu Chen, Peng Wu

Small· Volume 20· Issue 28
Publisher page
Source abstract

Abstract

Abstract Layered zeolitic silicates and corresponding interlayer‐expanded porous materials exhibit attractive application potential in wide fields. Nonetheless, designable synthesis and structure analysis of layered silicates remain challenging. Herein, two kinds of layered silicates are synthesized using different di‐quaternary ammonium‐type organic structure‐directing agents (OSDAs). Their crystal structures are analyzed and verified by 3D electron diffraction (3D ED) and high‐resolution TEM imaging. The suitable configurations of OSDA can lead to desirable interlayer states. Additionally, two new zeolite structures both with 12‐membered ring (MR) channels intersected by 8 MR channels and larger interlayer spaces are constructed from layered silicate precursors by interlayer silylation. The new zeolitic material exhibits potential application in adsorption of organic pollution and catalytic reaction. This study is expected to develop versatile ways for the design and synthesis of layered silicates even zeolites and provide references in characterizing layered materials and zeolites as well.
Source: crossref · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Chemical Synthesis and Characterization · Metal-Organic Frameworks: Synthesis and Applications · Zeolite Catalysis and Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, College of Chemistry and Materials Science Huaibei Normal University Huaibei Anhui 235000 P. R. China

Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University North Zhongshan Rd. 3663 Shanghai 200062 P. R. China

School of Chemistry University of St Andrews St Andrews Fife KY16 9ST UK

Shanghai Key Laboratory of High‐resolution Electron Microscopy ShanghaiTech University Shanghai 201210 P. R. China

Institute of Eco‐Chongming Shanghai 202162 P. R. China

Funding

Anhui Provincial Department of Education · Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · University Natural Science Research Project of Anhui Province

References (48)

Show source-provided references
1. 10.1039/C8TA04790A10.1039/C8TA04790A ↗
2. 10.1016/j.micromeso.2017.02.03410.1016/j.micromeso.2017.02.034 ↗
3. 10.1039/C7DT00698E10.1039/C7DT00698E ↗
4. 10.1021/acsaelm.0c0085610.1021/acsaelm.0c00856 ↗
5. 10.1021/am500515p10.1021/am500515p ↗
6. 10.1039/b617361f10.1039/b617361f ↗
7. 10.1002/anie.20046016810.1002/anie.200460168 ↗
8. 10.1002/anie.20180553510.1002/anie.201805535 ↗
9. 10.1126/science.aal012110.1126/science.aal0121 ↗
10. 10.1021/cr500010r10.1021/cr500010r ↗
11. 10.1021/cm303528u10.1021/cm303528u ↗
12. 10.1021/ic102006510.1021/ic1020065 ↗
13. 10.1016/j.micromeso.2004.06.00710.1016/j.micromeso.2004.06.007 ↗
14. 10.1515/zkri-2014-181010.1515/zkri-2014-1810 ↗
15. 10.1016/j.micromeso.2007.05.02110.1016/j.micromeso.2007.05.021 ↗
16. 10.1039/c2jm31872e10.1039/c2jm31872e ↗
17. 10.1016/j.micromeso.2014.10.00810.1016/j.micromeso.2014.10.008 ↗
18. 10.1039/C6DT02983C10.1039/C6DT02983C ↗
19. 10.1002/anie.20046008510.1002/anie.200460085 ↗
20. 10.1021/cm702880p10.1021/cm702880p ↗
21. 10.1016/j.ccr.2020.21358310.1016/j.ccr.2020.213583 ↗
22. 10.1002/anie.20191248810.1002/anie.201912488 ↗
23. 10.1002/anie.20201688210.1002/anie.202016882 ↗
24. 10.1524/zkri.2010.120210.1524/zkri.2010.1202 ↗
25. 10.1021/acs.chemrev.1c0020710.1021/acs.chemrev.1c00207 ↗
26. 10.1016/j.micromeso.2012.02.02410.1016/j.micromeso.2012.02.024 ↗
27. 10.1038/nature0795710.1038/nature07957 ↗
28. 10.1107/S205327331909211810.1107/S2053273319092118 ↗
29. 10.1021/jacs.9b0489510.1021/jacs.9b04895 ↗
30. 10.1021/acs.chemmater.2c0174410.1021/acs.chemmater.2c01744 ↗
31. 10.1038/s41467-022-34237-110.1038/s41467-022-34237-1 ↗
32. 10.1021/jp206017j10.1021/jp206017j ↗
33. 10.1039/C4DT00120F10.1039/C4DT00120F ↗
34. 10.1021/jp107958610.1021/jp1079586 ↗
35. 10.1016/j.micromeso.2022.11184310.1016/j.micromeso.2022.111843 ↗
36. 10.1107/S160057671500113210.1107/S1600576715001132 ↗
37. 10.1107/S002188980804272610.1107/S0021889808042726 ↗
38. 10.1021/acsami.5b0799610.1021/acsami.5b07996 ↗
39. 10.1107/S205252061900753410.1107/S2052520619007534 ↗
40. 10.1515/zkri-2014-173710.1515/zkri-2014-1737 ↗
41. 10.1107/S002188980702923810.1107/S0021889807029238 ↗
42. 10.1002/cctc.20180004010.1002/cctc.201800040 ↗
43. 10.1039/D1QI01171E10.1039/D1QI01171E ↗
44. 10.1021/ja075873910.1021/ja0758739 ↗
45. Fowler C. E. · Chem. Commun. · 1997 · 18 · 769
46. 10.1021/jp507719y10.1021/jp507719y ↗
47. 10.1016/j.micromeso.2012.10.00510.1016/j.micromeso.2012.10.005 ↗
48. 10.1039/b905415d10.1039/b905415d ↗