Mesoporous Metal Fluoride Nanocomposite Films with Tunable Optical Properties Derived from Precursor Instability

Abstract The precisely tailored refractive index of optical materials is the key to utilizing and manipulating light during its propagation through the matrix, thereby improving their application performances. In this paper, mesoporous metal fluoride films with engineered composition (MgF₂:LaF₃) are demonstrated to achieve finely tunable refractive indices. These films are prepared using a precursor‐derived one‐step assembly approach via the simple mixing of precursor solutions (Mg(CF₃OO)₂ and La(CF₃OO)₃); then pores are formed simultaneously during solidification owing to the inherent instability of La(CF₃OO)₃. The mesoporous structures are realized through Mg(CF₃OO)₂ and La(CF₃OO)₃ ions, which interacted with each other based on their electrostatic forces, providing a wide range of refractive indices (from 1.37 to 1.16 at 633 nm). Furthermore, it is systematically several MgF_2(1‐x)‐LaF_3(x) layers with different compositions (x = 0.0, 0.3, and 0.5) to form the graded refractive index coating that is optically consecutive between the substrate and the air for broadband and omnidirectional antireflection. An average transmittance of ≈98.03% (400–1100 nm) is achieved with a peak transmittance of ≈99.04% (at 571 nm), and the average antireflectivity is maintained at ≈15.75% even at an incidence of light of 65° (400–850 nm).