Achieving Ultralow Lattice Thermal Conductivity and High Thermoelectric Performance in Bi₂Te_2.7Se_0.3 Alloys via Introducing Organic & Inorganic Nanoparticles

Abstract N‐type Bi₂Te_2.7Se_0.3(BTS) is a state‐of‐the‐art thermoelectric material owing to its excellent thermoelectric properties near room temperatures for commercial applications. However, its performance is restricted by its comparatively low figure of merit ZT. Here, it is shown that a 14% increase in power factor (PF) (at 300 K) can be reached through incorporation of inorganic GaAs nanoparticles due to enhanced thermopower originating from the energy‐dependent carrier scattering. Besides, further incorporation of organic nanophase PEDOT: PSS can reduce its lattice thermal conductivity by 59% due to the strong scattering of middle‐ and low‐frequency phonons. As a result, a peak ZT value of ZT_max ≈ 1.31 (at 373 K) and an average ZT_ave ≈ 1.10 (300–473 K) are achieved for the BTS/(0.4 wt.% GaAs + 0.5 wt.% PEDOT: PSS) sample. The present work demonstrates that incorporation of organic–inorganic nanophase is an effective way to improve the performance of BTS.