Quasi‐Solid‐State All‐V₂O₅ Battery

Abstract Solid‐state symmetrical battery represents a promising paradigm for future battery technology. However, its development is hindered by the deficiency of high‐performance bipolar electrodes and compatible solid electrolytes. Herein, a quasi‐solid‐state all‐V₂O₅ battery constructed by a binder‐free carbon fabric‐V₂O₅ nanowires@graphene (CVOG) bipolar electrode and a softly cross‐linked polyethylene oxide‐based solid polymer electrolyte (SPE) is reported. The synergetic effect of nano‐structuring of V₂O₅, hierarchical conductive network, and graphene wrapping endows the CVOG electrode with boosted reaction kinetics and suppressed vanadium dissolution. The cathodic and anodic reactions of CVOG are decoupled by electrochemical analysis, conceiving the feasibility of constructing all‐V₂O₅ full battery. In manifesting the solid‐state all‐V₂O₅ battery, the robust and elastic SPE exhibits high ionic conductivity, tight/self‐adaptable electrolyte‐electrode contact, and a low charge‐transfer barrier. The resultant solid‐state full battery exhibits a high reversible capacity of 158 mAh g⁻¹ at 0.1 C, good capacity retention of over 61% from 0.1 C to 2 C, and remarkable cycling stability of 77% capacity retention after 1000 cycles at 1 C, which surpass other solid‐state symmetrical batteries. Hence, this work provides a practice of high‐performance solid‐state batteries with symmetrical configuration and is constructive for next‐generation battery technology.