Shaping Graphene Superconductivity with Nanometer Precision

Abstract Graphene holds great potential for superconductivity due to its pure 2D nature, the ability to tune its carrier density through electrostatic gating, and its unique, relativistic‐like electronic properties. At present, still far from controlling and understanding graphene superconductivity, mainly because the selective introduction of superconducting properties to graphene is experimentally very challenging. Here, a method is developed that enables shaping at will graphene superconductivity through a precise control of graphene‐superconductor junctions. The method combines the proximity effect with scanning tunnelling microscope (STM) manipulation capabilities. Pb nano‐islands are first grown that locally induce superconductivity in graphene. Using a STM, Pb nano‐islands can be selectively displaced, over different types of graphene surfaces, with nanometre scale precision, in any direction, over distances of hundreds of nanometres. This opens an exciting playground where a large number of predefined graphene‐superconductor hybrid structures can be investigated with atomic scale precision. To illustrate the potential, a series of experiments are performed, rationalized by the quasi‐classical theory of superconductivity, going from the fundamental understanding of superconductor‐graphene‐superconductor heterostructures to the construction of superconductor nanocorrals, further used as “portable” experimental probes of local magnetic moments in graphene.