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journal article·2024-01Open access

Toward Conductive Additive Free Organic Electrode for Lithium‐Ion Battery Using Supramolecular Columnar Organization

Vincent Pignier, Sylvestre Toumieux, Carine Davoisne, Maxandre Caroff, Arash Jamali, Serge Pilard, David Mathiron, Dominique Cailleu, François Delattre, Dharmendra Pratap Singh, Redouane Douali, Matthieu Becuwe

Small· Volume 20· Issue 4
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Source abstract

Abstract

Abstract With the aim to meet the greatest challenge facing organic batteries, namely the low conductivity of the electrodes, the electrochemical properties of a series of substituted perylene diimides able to form semi‐conductive columnar material are investigated. Depending on the substituent group, a strong influence of this group on the reversibility, redox potential but especially on the gravimetric capacity of the electrodes is observed. In the case of substitution by a simple propyl group, the corresponding diimide shows a complete electrochemical activity with only 10% by mass of conductive additive and even shows a half‐capacity activity without any additive and without particular electrode engineering. Extensive research has highlighted the intrinsic reactivity of the columnar material but also its perpetual rearrangement during charge/discharge cycles. This study shows that the amount of conductive additive can be significantly reduced by adapting the design of the molecular material and favoring the assembly of redox units in the form of a conductive column.
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Research context

Energy storage

OpenAlex topics: Conducting polymers and applications · Advancements in Battery Materials · Polyoxometalates: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratoire de Réactivité et Chimie des Solides (LRCS) UMR CNRS 7314 Université de Picardie Jules Verne Hub de l'Energie, 15 rue Baudelocque Amiens Cedex 80039 France

Laboratoire de Glycochimie des Antimicrobiens et des Agroressources (LG2A) UR 7378 Université de Picardie Jules Verne 10 rue Baudelocque Amiens Cedex 80039 France

Institut de Chimie de Picardie (ICP) FR CNRS 3085 Amiens 80039 France

Réseau sur le Stockage Electrochimique de l'Energie (RS2E) FR CNRS 3459, Hub de l'Energie, 15 rue Baudelocque Amiens Cedex 80039 France

Unité de Chimie Environnementale et Interactions sur le Vivant (UCEIV) UR 4492 Université du Littoral‐Côte d'Opale Dunkerque 59140 France

Plateforme de Microscopie Electronique – Université de Picardie Jules Verne HUB de l'Energie, 33 rue Saint Leu Amiens Cedex 80039 France

Plateforme Analytique Université de Picardie Jules Verne Amiens Cedex 80039 France

Unité de Dynamique et Structure des Matériaux Moléculaires (UDSMM) UR 4476 Université du Littoral Côte d'Opale Centre Universitaire de la Mi‐Voix, BP 699 Calais Cedex 62228 France

References (46)

Show source-provided references
1. 10.1038/ngeo199310.1038/ngeo1993 ↗
2. 10.1016/j.jclepro.2019.11782010.1016/j.jclepro.2019.117820 ↗
3. 10.1021/acs.chemrev.9b0048210.1021/acs.chemrev.9b00482 ↗
4. 10.1021/acsami.6b0759110.1021/acsami.6b07591 ↗
5. 10.1039/c3ee40878g10.1039/c3ee40878g ↗
6. 10.1038/srep0267110.1038/srep02671 ↗
7. 10.1021/ja902489710.1021/ja9024897 ↗
8. 10.1002/batt.20230009010.1002/batt.202300090 ↗
9. 10.1038/s41570-020-0160-910.1038/s41570-020-0160-9 ↗
10. 10.1002/aesr.20200004410.1002/aesr.202000044 ↗
11. 10.1021/acs.chemrev.2c0037410.1021/acs.chemrev.2c00374 ↗
12. 10.1016/j.joule.2018.07.00810.1016/j.joule.2018.07.008 ↗
13. 10.1016/j.jpowsour.2020.22881410.1016/j.jpowsour.2020.228814 ↗
14. 10.1016/j.jcis.2018.01.09510.1016/j.jcis.2018.01.095 ↗
15. 10.1021/acsnano.7b0231010.1021/acsnano.7b02310 ↗
16. 10.1039/C3QI00076A10.1039/C3QI00076A ↗
17. 10.1039/c3cc39065a10.1039/c3cc39065a ↗
18. 10.1021/nl402239p10.1021/nl402239p ↗
19. 10.1002/batt.20190016410.1002/batt.201900164 ↗
20. 10.1039/C6TA02356H10.1039/C6TA02356H ↗
21. 10.1021/acsami.0c0364210.1021/acsami.0c03642 ↗
22. 10.1021/acsaem.1c0357410.1021/acsaem.1c03574 ↗
23. 10.1021/acs.chemrev.5b0019010.1021/acs.chemrev.5b00190 ↗
24. 10.1021/jp206847810.1021/jp2068478 ↗
25. 10.1021/ja053225o10.1021/ja053225o ↗
26. 10.1021/acs.jpcc.8b0219910.1021/acs.jpcc.8b02199 ↗
27. 10.1063/1.146770610.1063/1.1467706 ↗
28. 10.1039/D0TC02754E10.1039/D0TC02754E ↗
29. 10.1039/B512983D10.1039/B512983D ↗
30. 10.1016/j.solmat.2009.11.02410.1016/j.solmat.2009.11.024 ↗
31. 10.1016/j.orgel.2018.08.04110.1016/j.orgel.2018.08.041 ↗
32. 10.1039/C6TA02880B10.1039/C6TA02880B ↗
33. 10.1039/c3ta10473g10.1039/c3ta10473g ↗
34. 10.1039/D2SC02939A10.1039/D2SC02939A ↗
35. 10.1002/slct.20180158810.1002/slct.201801588 ↗
36. 10.1021/jz401735910.1021/jz4017359 ↗
37. 10.1016/j.electacta.2017.02.15210.1016/j.electacta.2017.02.152 ↗
38. 10.1039/C8TA03186J10.1039/C8TA03186J ↗
39. 10.1002/adma.20060258410.1002/adma.200602584 ↗
40. 10.1002/adsu.20160003210.1002/adsu.201600032 ↗
41. 10.1039/C4TA02293A10.1039/C4TA02293A ↗
42. 10.1021/acs.chemmater.6b0352410.1021/acs.chemmater.6b03524 ↗
43. 10.1007/s10895-015-1725-810.1007/s10895-015-1725-8 ↗
44. 10.1002/qua.2071210.1002/qua.20712 ↗
45. 10.1590/1980-5373-mr-2016-069210.1590/1980-5373-mr-2016-0692 ↗
46. 10.1002/jlac.19801980121010.1002/jlac.198019801210 ↗