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journal article·2023-09Open access

Lithium Foam for Deep Cycling Lithium Metal Batteries

Aoxuan Wang, Kaixin Zhang, Linxue Zhang, Qingtao Ma, Shoubin Zhou, Qinhai Jiang, Zhenglin Hu, Jiayan Luo

Small· Volume 19· Issue 36
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Source abstract

Abstract

Abstract Li metal anode has been recognized as the most promising anode for its high theoretical capacity and low reduction potential. But its large‐scale commercialization is hampered because of the infinite volume expansion, severe side reactions, and uncontrollable dendrite formation. Herein, the self‐supporting porous lithium foam anode is obtained by a melt foaming method. The adjustable interpenetrating pore structure and dense Li3N protective layer coating on the inner surface enable the lithium foam anode with great tolerance to electrode volume variation, parasitic reaction, and dendritic growth during cycling. Full cell using high areal capacity (4.0 mAh cm−2) LiNi0.8Co0.1Mn0.1 (NCM811) cathode with the N/P ratio of 2 and E/C ratio of 3 g Ah−1 can stably operate for 200 times with 80% capacity retention. The corresponding pouch cell has <3% pressure fluctuation per cycle and almost zero pressure accumulation.
Source: crossref · Quality: baseline

Research context

Energy storage

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China

State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of Chemistry Xinjiang University Urumqi 830017 China

HuaFu High Technology Energy Storage CO. LTD Yangzhou 225600 China

Shanghai Key Lab of Advanced High‐temperature Materials and Precision Forming State Key Lab of Metal Matrix Composites School of Materials Science and Engineering Shanghai Jiao Tong University Shanghai 200240 China

Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Molecular Engineering Shaoxing 312000 China

Funding

National Key Research and Development Program of China · National Natural Science Foundation of China · Natural Science Foundation of Tianjin City

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