Photothermal‐Driven High‐Performance Selective Hydrogenation System Enabled by Delicately Designed IrCo Nanocages

Abstract The incorporation of a transition metal into a noble metal for the formation of nanoalloys paves a potential way to modulate the electronic structures and spatial arrangement modes, thereby manipulating the target catalysis under the desired reaction pathways. Herein, a top‐down synthetic route to fabricate IrCo nanoalloys with delicately designed compositions and morphologies at an extremely low calcination temperature of 200 °C is reported, which efficiently breaks through the thermodynamic limitations caused by the large atomic radii and electronegativity discrepancies between Co and Ir. A high‐performance selective hydrogenation system enabled by the synthesized IrCo nanoalloys and the light irradiation is further established. Significantly, the unique properties of IrCo alloy, involving the special capability of generating local heating rather than hot electrons under light irradiation (the hot‐electron effect was considered detrimental to hydrogenation reactions), as well as the highly polarized surface which aids in the hydrogen transfer from borane‐ammonia complex (AB) to 4‐nitrostyrene (4‐NS) are discovered.