journal article·2025-05Open access

Non‐Aqueous Electrochemical CO 2 Reduction to Multivariate C 2 ‐Products Over Single Atom Catalyst at Current Density up to 100 mA cm −2 (Small 18/2025)

Rajan R. Bhawnani, Rohan Sartape, Vamsi V Gande, Michael L. Barsoum, Elias M. Kallon, Roberto dos Reis, Vinayak P. Dravid, Meenesh R. Singh

Small· Volume 21· Issue 18

Abstract

CO2 Reduction In article number 2408010, Meenesh R. Singh and co-workers explore a conductive, stable Zr-based porphyrin metal–organic framework (MOF), PCN-222, metalated with single-atom Cu for CO2 reduction. PCN-222(Cu) achieves ∼100 mA cm−2 current density and 40% faradaic efficiency for acetate, outperforming previous MOF systems. X-ray and spectroscopic analyses provide key insights into its catalytic mechanism, advancing MOF-based single-atom catalysis.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Machine Learning in Materials Science · Ionic liquids properties and applications

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Affiliations

Department of Chemical Engineering University of Illinois Chicago Chicago IL 60607 USA

Department of Materials Science & Engineering Northwestern University Evanston IL 60208 USA

International Institute of Nanotechnology Northwestern University Evanston IL 60208 USA

The NUANCE Center Northwestern University Evanston IL 60208 USA

References

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