Rapidly Prepared Lithophilic Frameworks Stabilizes Lithium Anodes via Altered Lithium Deposition Patterns

Abstract Lithium metal batteries are regarded as promising candidates for next‐generation energy storage systems. However, their anodes are susceptible to interfacial instability due to significant volume changes, which significantly impacts the cycle life of lithium metal batteries. Here, a rapid method for the fabrication of 3D‐hosts with interface modified layers is reported. A simple infiltration and heating process enables the transformation of copper foam into Zn‐BDC‐modified copper foam within 1 min, rendering it suitable for use as a current collector for lithium metal anodes. The Zn‐BDC nanosheets with high lithiophilicity are uniformly distributed on the surface of the current collector, facilitating the uniform deposition of lithium and reducing the volume change. Consequently, the half cell exhibits a remarkably low overpotential (26 mV) at a current–density of 4 mA cm⁻² and is cycled stably for 1000 h. Furthermore, it demonstrates a significant enhancement in performance in the LiFePO₄ full cell. This study provides a crucial reference on the connection between the interfacial modification of the current collector and the lithium deposition behavior, which promotes the practicalization of lithium metal anodes.