Polymer‐Grafted, Gold Nanoparticle‐Based Nano‐Capsules as Reversible Colorimetric Tensile Strain Sensors

Abstract Colloidal colorimetric microsensors enable the in‐situ detection of mechanical strains within materials. Enhancing the sensitivity of these sensors to small scale deformation while enabling reversibility of the sensing capability would expand their utility in applications including biosensing and chemical sensing. In this study, we introduce the synthesis of colloidal colorimetric nano‐sensors using a simple and readily scalable fabrication method. Colloidal nano sensors are prepared by emulsion‐templated assembly of polymer‐grafted gold nanoparticles (AuNP). To direct the adsorption of AuNP to the oil‐water interface of emulsion droplets, AuNP (≈11nm) are functionalized with thiol‐terminated polystyrene (PS, M_n = 11k). These PS‐grafted gold nanoparticles are suspended in toluene and subsequently emulsified to form droplets with a diameter of ≈30µm. By evaporating the solvent of the oil‐inwater emulsion, we form nanocapsules (AuNC) (diameter < 1µm) decorated by PS‐grafted AuNP. To test mechanical sensing, the AuNC are embedded in an elastomer matrix. The addition of a plasticizer reduces the glass transition temperature of the PS brushes, and in turn imparts reversible deformability to the AuNC. The plasmonic peak of the AuNC shifts towards lower wavelengths upon application of uniaxial tensile tension, indicating increased inter‐nanoparticle distance, and reverts back as the tension is released.