A new In Situ Oxidized 2D Layered MnBi₂Te₄ Cathode for High‐Performance Aqueous Zinc‐Ion Battery

Abstract Recently, aqueous zinc ion batteries (AZIBs) with the superior theoretical capacity, high safety, low prices, and environmental protection, have emerged as a contender for advanced energy storage. However, challenges related to cathode materials, such as dissolution, instability, and structural collapse, have hindered the progress of AZIBs. Here, a novel AZIB is constructed using an oxidized 2D layered MnBi₂Te₄ cathode for the first time. The oxidized MnBi₂Te₄ cathode with large interlayer spacing and low energy barrier for zinc ion diffusion at 240 °C, exhibited impressive characteristics, including a high reversibility capacity of 393.1 mAh g⁻¹ (0.4 A g⁻¹), outstanding rate performance, and long cycle stability. Moreover, the corresponding aqueous button cell also exhibits excellent electrochemical performance. To demonstrate the application in practice in the realm of flexible wearable electronics, a quasi‐solid‐state micro ZIB (MZIB) is constructed and shows excellent flexibility and high‐temperature stability (the capacity does not significantly degrade when the temperature reaches 100 °C and the bending angle exceeds 150°). This research offers effective tactics for creating high‐performance cathode materials for AZIBs.