Nano‐Confined Effect and Heterojunction Promoted Exciton Separation for Light‐Boosted Osmotic Energy Conversion

Abstract The osmotic energy conversion properties of biomimetic light‐stimulated nanochannels have aroused great interest. However, the power output performance is limited by the low light‐induced current and energy conversion efficiency. Here, nanochannel arrays with simultaneous modification of ZnO and di‐tetrabutylammonium cis‐bis(isothiocyanato)bis(2,20‐bipyridyl‐4,40‐dicarboxylato) ruthenium (II) (N719) onto anodic aluminum oxide (AAO) to combine the nano‐confined effect and heterojunction is designed, which demonstrate rectified ion transport behavior due to the asymmetric composition, structure and charge. High cation selectivity and ion flux contribute to the high power density of ≈7.33 W m⁻² by mixing artificial seawater and river water. Under light irradiation, heterojunction promoted the production and separation of exciton, enhanced cation selectivity, and improved the utilization efficiency of osmotic energy, providing a remarkable power density of ≈18.49 W m⁻² with an increase of 252% and total energy conversion efficiency of 30.43%. The work opens new insights into the biomimetic nanochannels for high‐performance energy conversion.