journal article·2016-04

Toward Scalable Fabrication of Hierarchical Silica Capsules with Integrated Micro‐, Meso‐, and Macropores

Weizheng Zhou, Gangsheng Tong, Dali Wang, Bangshang Zhu, Yu Ren, Michael Butler, Eddie Pelan, Deyue Yan, Xinyuan Zhu, Simeon D. Stoyanov

Small· Volume 12· Issue 13
Publisher page

Abstract

Hierarchical porous structures are ubiquitous in biological organisms and inorganic systems. Although such structures have been replicated, designed, and fabricated, they are often inferior to naturally occurring analogues. Apart from the complexity and multiple functionalities developed by the biological systems, the controllable and scalable production of hierarchically porous structures and building blocks remains a technological challenge. Herein, a facile and scalable approach is developed to fabricate hierarchical hollow spheres with integrated micro‐, meso‐, and macropores ranging from 1 nm to 100 μm (spanning five orders of magnitude). (Macro)molecules, micro‐rods (which play a key role for the creation of robust capsules), and emulsion droplets have been successfully employed as multiple length scale templates, allowing the creation of hierarchical porous macrospheres. Thanks to their specific mechanical strength, these hierarchical porous spheres could be incorporated and assembled as higher level building blocks in various novel materials.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Pickering emulsions and particle stabilization · Polymer Surface Interaction Studies · Mesoporous Materials and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University Shanghai 200240 P. R. China

Unilever Research and Development Shanghai Shanghai 200335 P. R. China

Instrumental Analysis Center Shanghai Jiao Tong University Shanghai 200240 P. R. China

BASF Battery Materials Shanghai 201206 P. R. China

Unilever Research and Development Colworth Colworth Science Park Sharnbrook MK44 1LQ UK

Unilever Research and Development Vlaardingen Vlaardingen 3133 AT Netherlands

Physical Chemistry and Soft Matter Wageningen University Wageningen 6703 HB Netherlands

Department of Mechanical Engineering University College London Torrington Place London WC1E 7JE UK

Funding

National Basic Research Program · National Natural Science Foundation of China

References (33)

Show source-provided references
1. 10.1039/C2CS35308C10.1039/C2CS35308C ↗
2. 10.1002/adma.20080364510.1002/adma.200803645 ↗
3. 10.1039/c3cs35345a10.1039/c3cs35345a ↗
4. 10.1039/C2CS35378D10.1039/C2CS35378D ↗
5. 10.1002/adma.20100239510.1002/adma.201002395 ↗
6. 10.1016/j.mser.2014.04.00110.1016/j.mser.2014.04.001 ↗
7. 10.1038/nmat142110.1038/nmat1421 ↗
8. 10.1002/adma.20120533210.1002/adma.201205332 ↗
9. 10.1002/1521-4095(20021203)14:23<1768::AID-ADMA1768>3.0.CO;2-010.1002/1521-4095(20021203)14:23<1768::AID-ADMA1768>3.0.CO;2-0 ↗
10. Ren Y. · Nat. Commun. · 2013 · 4 · 2015/1
11. 10.1038/nmat191210.1038/nmat1912 ↗
12. 10.1039/c3cc45323e10.1039/c3cc45323e ↗
13. 10.1021/jp810812210.1021/jp8108122 ↗
14. 10.1021/cm103704s10.1021/cm103704s ↗
15. 10.1002/adma.20039001710.1002/adma.200390017 ↗
16. 10.1039/c0cc03511d10.1039/c0cc03511d ↗
17. 10.1016/j.progpolymsci.2013.08.00610.1016/j.progpolymsci.2013.08.006 ↗
18. 10.1039/b719709h10.1039/b719709h ↗
19. Liang Y. · Sci. Rep. · 2013 · 3 · 1119/1
20. 10.1007/s11661-010-0477-y10.1007/s11661-010-0477-y ↗
21. 10.1021/cm900874u10.1021/cm900874u ↗
22. 10.1039/b102675p10.1039/b102675p ↗
23. 10.1126/science.273.5276.76810.1126/science.273.5276.768 ↗
24. 10.1039/C2TA00451H10.1039/C2TA00451H ↗
25. 10.1021/la904339610.1021/la9043396 ↗
26. 10.1002/anie.20080419410.1002/anie.200804194 ↗
27. 10.1039/c2jm33220e10.1039/c2jm33220e ↗
28. 10.1039/C0CC03599H10.1039/C0CC03599H ↗
29. 10.1002/anie.20100751910.1002/anie.201007519 ↗
30. 10.1016/j.colsurfa.2013.01.00710.1016/j.colsurfa.2013.01.007 ↗
31. 10.1016/j.micromeso.2007.05.00910.1016/j.micromeso.2007.05.009 ↗
32. 10.1016/j.materresbull.2012.01.01410.1016/j.materresbull.2012.01.014 ↗
33. 10.1021/la034785910.1021/la0347859 ↗