Generation of Complex Tunable Multispectral Signatures with Reconfigurable Protein‐Based, Plasmonic‐Photonic Crystal Hybrid Nanostructures

Abstract Structurally colored materials, which rely on the interaction between visible light and nanostructures, produce brilliant color displays through fine control of light interference, diffraction, scattering, or absorption. Rationally combining different color‐selective functions into a single form offers a powerful strategy to create programmable optical functions which are otherwise difficult, if not impossible to obtain. By leveraging structural protein templates, specifically silk fibroin, nanostructured materials that combine plasmonic and photonic crystal paradigms are shown here. This confluence of function enables directional, tunable, and multiple co‐located optical responses derived from the interplay between surface plasmon resonance and photonic bandgap effects. Several demonstrations are shown with programmable coloration at varying viewing sides, angle, and by solvent infiltration, opening avenues for smart displays and multi‐mode information encoding applications.