Light‐Governed Capillary Flow in Microfluidic Systems

Abstract Light‐based flow systems for point‐of‐care devices are of interest because, in principle, sunlight could be used to operate them, potentially allowing for high functionality with minimal device complexity and expense. A light‐operated method to drive flow using poly(N‐isopropylacrylamide), a ‘smart’ polymer that changes wettability as a function of temperature, is introduced. It is grafted onto a carbon black‐polydimethylsiloxane surface, which converts light into a thermal pattern that valves flow at user‐defined locations. Flow rates are demonstrated ranging from 4 μL min⁻¹ at 25 °C to 0.1 μL min⁻¹ at 40 °C. The valving dynamics are also characterised, and a response time of less than 4 s is shown. Light‐operated flow could provide the simple architecture and advanced functionality needed in low‐resource point‐of‐care devices.