Chiroptical Transitions of Enantiomeric Ligand‐Activated Nickel Oxides
Source abstract
Abstract
Abstract Ligand‐induced chirality in transition‐metal oxide (TMO) nanostructures have great potential for designing materials with tunable chiroptical effects. Herein, a facile strategy is reported to prepare chiroptical active nickel‐oxide hybrids combined with pH adjustment, and the redox treatment results in ligand transformation, which is attributable to multiple optical transitions in the TMO nanostructures. The theoretical calculation also explains the chiral origins based on their complex models based on empirical analysis. It is also shown that enantiomeric TMO nanoparticles can be used as chiral inducers for chiroptical sensitive polymerization. These results demonstrate that TMO nanostructures can provide rational control over photochemical synthesis and chiral transfer of inorganics nanoarchitecture chirality.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Polydiacetylene-based materials and applications · Luminescence and Fluorescent Materials · Supramolecular Self-Assembly in Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Materials Science and Engineering Hubei University Wuhan 430062 China
College of Physics and Optoelectronic Engineering Shenzhen University Shenzhen 518060 China
School of Science and Engineering The Chinese University of Hong Kong Shenzhen 518172 China
Department of Chemistry Purdue University West Lafayette IN 47906 USA
Key Laboratory of Cell Biology Ministry of Public Health and Key Laboratory of Medical Cell Biology Ministry of Education China Medical University Shenyang 110122 China
Funding
Department of Education of Guangdong Province
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