Weakening Circular Dichroism of Plasmonic Nanospirals Induced by Surface Grafting with Alkyl Ligands

Silver nanospirals with strong chiroptical activity (characterized by circular dichroism) are grafted with achiral alkyl ligands, resulting in a weakening of the chiroptical activity. The chiroptical weakening is exacerbated with increasing bond energy of the Ag-ligand contacts, which is ascribed to the effective medium screening effect and electron withdrawal toward the alkyl ligands. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.