journal article·2019-05

Polymer Brushes on Hexagonal Boron Nitride

Wenbo Sheng, Ihsan Amin, Christof Neumann, Renhao Dong, Tao Zhang, Erik Wegener, Wei‐Liang Chen, Paul Förster, Hai Quang Tran, Markus Löffler, Andreas Winter, Raul D. Rodriguez, Ehrenfried Zschech, Christopher K. Ober, Xinliang Feng, Andrey Turchanin, Rainer Jordan

Small· Volume 15· Issue 19
Publisher page

Abstract

Abstract Direct covalent functionalization of large‐area single‐layer hexagonal boron nitride (hBN) with various polymer brushes under mild conditions is presented. The photopolymerization of vinyl monomers results in the formation of thick and homogeneous (micropatterned, gradient) polymer brushes covalently bound to hBN. The brush layer mechanically and chemically stabilizes the material and allows facile handling as well as long‐term use in water splitting hydrogen evolution reactions.
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Research context

OpenAlex topics: Graphene research and applications · 2D Materials and Applications · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Chair of Macromolecular Chemistry School of Science Technische Universität Dresden Mommsenstr. 4 01069 Dresden Germany

Junior Research Group Biosensing Surfaces Leibniz Insitute for Plasma Science and Technology (INP) Felix‐Hausdorff‐Str. 2 17489 Greifswald Germany

Department of Materials Science and Engineering Cornell University 310 Bard Hall Ithaca NY 14853 USA

Institute of Physical Chemistry Friedrich Schiller University Jena Center for Energy and Environmental Chemistry Jena (CEEC Jena) Lessingstr. 10 07743 Jena Germany

Chair of Molecular Functional Materials School of Science Technische Universität Dresden Mommsenstr. 4 01069 Dresden Germany

Robert Frederick Smith School of Chemical and Biomolecular Engineering Cornell University 120 Olin Hall Ithaca NY 14853 USA

Dresden Center for Nanoanalysis Center for Advancing Electronics Dresden (CfAED) Technische Universität Dresden Helmholtzstr. 18 01187 Dresden Germany

Research School of Chemistry & Applied Biomedical Sciences Tomsk Polytechnic University 30 Lenin Ave 634050 Tomsk Russia

Department Head Microelectronic Materials and Nanoanalysis Fraunhofer Institute for Ceramic Technologies and Systems Maria Reiche Str. 2 01099 Dresden Germany

Funding

National Science Foundation

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