Varying Voltage Performance of Zn²⁺/H⁺ Co‐Storage Caused by Active Site Restriction in Aqueous Zinc‐Organic Batteries

Abstract Imine‐carbonyl compounds show high‐capacity due to Zn²⁺/H⁺ co‐storage, however, the impact of C═N and C═O interactions on Zn²⁺/H⁺ coordination remains underexplored. To address this, small organic molecules with the same number of active sites but differing positions of C═O and C═N groups are designed and selected. It is found that different relative positions cause spatial restriction of the C═N active site, making the bonding mode of zinc ions shift from N─Zn─O to O─Zn─O. Moreover, O─Zn─O exhibits a larger bond order and higher stability compared to N─Zn─O. The larger bond order enhanced the stability of the reduction products, resulting in better battery cycling performance. In addition, the co‐storage of Zn²⁺/H⁺ reduces the Gibbs free energy change of the reaction, increases the discharge voltage, and results in a flatter discharge plateau. This study serves as an important guide for designing high‐performance organic cathode materials.