Efficient Capture and Separation of Xenon/Krypton from Off‐Gas by a Radiation‐Resistant Metal–Organic Framework

Abstract The capture of xenon (Xe) and krypton (Kr) from the off‐gas of used nuclear fuel is of great importance to the treatment of radioactive wastes and production of high purity Xe. Solid sorbents, in particular metal–organic frameworks (MOFs), show promise in gas capture. However, the unknown radiation resistance of MOFs has limited their development. Herein, the efficient capture and separation of Xe/Kr by MFM‐520, which strikes a remarkable stability toward 1750 kilogray (kGy) γ‐irradiation, is reported. Under ambient conditions, dynamic breakthrough experiments confirm the efficient separation performance, yielding a Xe capacity of 66 and 0.2 mg g ⁻¹ from a by‐product of air separation (Xe/Kr: 20/80; v/v) and off‐gas (Xe/Kr: 400/40 ppm balance in air), respectively. In situ synchrotron X‐ray single crystal diffraction and solid‐state nuclear magnetic resonance (ssNMR) studies reveal that the optimal micropore of MFM‐520 underpins specific host‐guest interactions to Xe, resulting in selective Xe capture.