Ultra‐Low Alginate‐Based Multifunctional Composite Binders for Enhanced Mechanical, Electrochemical, and Thermal Performance of Li–S Batteries

Abstract The practical application of Li–S batteries, which hold great potential as energy storage devices, is impeded by various challenges, such as capacity degradation caused volume change, polysulfide shuttling, poor electrode kinetics, and safety concerns. Binder plays a crucial role in suppressing volume change of cathode side, thereby enhancing the electrochemical performance of Li–S batteries. In this research, a novel network binder (SA‐Co‐PEDOT) composed of sodium alginate is presented, Co²⁺ ions as cross‐linking agent and PEDOT as an electronic conductor. The theoretical analysis and experimental testing confirm that the SA‐Co‐PEDOT binder with synergistic combination of catalytic center and electron transfer network effectively mitigates large volumetric changes during cycling while simultaneously enhancing electrode kinetics through controlling the deposition morphology of sulfur end product and its nucleation and dissolution. As a result, it achieves a capacity of 844 mAh g⁻¹ after 150 cycles at 0.2 C. Moreover, the electrode with SA‐Co‐PEDOT binder subjected a bending test maintains a capacity of 395 mAh g⁻¹ after 500 cycles at 0.5 C, exhibiting an impressively low decay rate of only 0.11%. Even with an ultra‐low content of 2 wt.% SA‐Co‐PEDOT binder, the electrode still maintains a capacity of 999.7 mAh g⁻¹ after 100 cycles at 0.5 C.