Atomically Precise Metal–Metal Oxide Interface in Polyoxometalate‐Noble Metal Hybrid Clusters

Abstract Metal‐metal oxide hybrid materials, typically composed of metal nanoparticles anchored on metal oxides matrix, are devoted enormous attentions as famous heterogeneous catalysts. The interactions between noble metals and metal oxides as well as their interfaces have been proven to be the origin of their excellent catalytic performance. Deep understandings on the interactions between noble metals and metal oxides at atomic precision, thus to precisely assess their contributions to catalysis, can serve as basic principles for catalyst design. In recent years, polyoxometalates (POMs), which in principle can be regarded as atomically precise metal oxide clusters, have been shown to have strong affinity to noble metals, thus forming diverse kinds of POM‐noble metal hybrid clusters. Their well‐resolved atomically precise structures and hybrid nature promise them as ideal platforms to understand the interfaces and interactions between noble metals and metal oxides. In this review, metal‐metal oxide interface is classified into different categories based on the different configurations of hybrid clusters, and aims to understand the interface structures and electronic correlations between POMs and noble metals at the atomic precision. Based on these basic understandings, the study provides the perspectives on the challenges and research efforts to be paid in the future.