Direct Exfoliation of Nanoribbons from Bulk van der Waals Crystals

Abstract Confinement of monolayers into quasi‐1D atomically thin nanoribbons could lead to novel quantum phenomena beyond those achieved in their bulk and monolayer counterparts. However, current experimental availability of nanoribbon species beyond graphene is limited to bottom‐up synthesis or lithographic patterning. In this study, a versatile and direct approach is introduced to exfoliate bulk van der Waals crystals as nanoribbons. Akin to the Scotch tape exfoliation method for producing monolayers, this technique provides convenient access to a wide range of nanoribbons derived from their corresponding bulk crystals, including MoS ₂ , WS ₂ , MoSe ₂ , WSe ₂ , MoTe ₂ , WTe ₂ , ReS ₂ , and hBN. The nanoribbons are predominantly monolayer, single‐crystalline, parallel‐aligned, flat, and exhibit high aspect ratios. The role of confinement, strain, and edge configuration of these nanoribbons is observed in their electrical, magnetic, and optical properties. This versatile exfoliation technique provides a universal route for producing a variety of nanoribbon materials and supports the study of their fundamental properties and potential applications.