Au@Ag Nanopencil with Au Tip and Au@Ag Rod: Multimodality Plasmonic Nanoprobe based on Asymmetric Etching for the Detection of SCN⁻ and ClO⁻

Abstract In this paper, Au@Ag nanopencil is designed as a multimodality plasmonic nanoprobe based on asymmetric etching for the detection of SCN⁻ and ClO⁻. Au@Ag nanopencil with Au tip and Au@Ag rod is prepared by asymmetric tailoring of uniformly grown silver‐covered gold nanopyramids under the combined effect of partial galvanic replacement and redox reaction. By asymmetric etching in different systems, Au@Ag nanopencil exhibits diversified changes in the plasmonic absorption band: O₂^•− facilitated by SCN⁻ etches Au@Ag rod from the end to the tip, causing a blue shift of the localized surface plasmon resonance (LSPR) peak as the aspect ratio decreases; while the ClO⁻ can retain Au@Ag shell and etch Ag within rod from the tip to the end, causing a redshift of the LSPR peak as the coupling resonance weakens. Based on peak shifts in different directions, a multimodality detection of SCN⁻ and ClO⁻ has been established. The results demonstrate the detection limits of SCN⁻ and ClO⁻ are 160 and 6.7 nm, and the linear ranges are 1–600 µm and 0.05–13 µm, respectively. The finely designed Au@Ag nanopencil not only broadens the horizon of designing heterogeneous structures, but also enriches the strategy of constructing multimodality sensing platform.