AgNWs/Fe₃O₄@NC Conductive Network Hierarchical Assembly to Prepare Flexible EMI Shielding Textile

Abstract With the rapid development of high‐power electronic instruments and communication technology, efficient electromagnetic shielding materials with strong absorption of electromagnetic waves and low reflection characteristics have become the focus of the world's attention. This study designs and synthesizes N‐doped carbon‐coated hollow Fe₃O₄ nanospheres (Fe₃O₄@NC) by spraying Ag nanowires (AgNWs) on textiles as conductive networks. Because of the high permeability and hollow structure Fe₃O₄@NC, electromagnetic wave goes through a unique process of “absorption, reflection, and reabsorption” when it passes through the surface of the composite textile. In X‐band (≈8.2–12.4 GHz), the average electromagnetic interference shielding effectiveness (EMI SE) reaches 50.1 dB, while the reflectance shielding efficiency (SE_R) is only 2.6 dB, and the average reflectance power coefficient (R) is as low as 0.45. The composite fabric has excellent properties and provides an effective strategy for electromagnetic interference shielding based on absorption.