Engineering of Cerium Modified TiNb₂O₇ Nanoparticles For Low‐Temperature Lithium‐Ion Battery

Abstract Although TiNb₂O₇ (TNO) with comparable operating potential and ideal theoretical capacity is considered to be the most ideal replacement for negative Li₄Ti₅O₁₂ (LTO), the low ionic and electronic conductivity still limit its practical application as satisfactory anode for lithium‐ion batteries (LIBs) with high‐power density. Herein, TNO nanoparticles modified by Cerium (Ce) with outstanding electrochemical performance are synthesized. The successful introduction of Ce³⁺ in the lattice leads to increased interplanar spacing, refined grain size, more oxygen vacancy, and a smaller lithium diffusion barrier, which are conducive to improve conductivity of both Li⁺ and electrons. As a result, the modified TNO reaches high reversible capacity of 256.0 mA h g⁻¹ at 100 mA g⁻¹ after 100 cycles, and 183.0 mA h g⁻¹ even under 3200 mA g⁻¹. In particular, when the temperature drops to −20 °C, the cell undergoing 1500 cycles at a high current density of 500 mA g⁻¹ can still reach 89.7 mA h g⁻¹, corresponding to a capacity decay rate per cycle of only 0.033%. This work provides a new way to improve the electrochemical properties of alternative anodes for LIBs at extreme temperature.