Highly Dispersed Ru–Co Nanoparticles Interfaced With Nitrogen‐Doped Carbon Polyhedron for High Efficiency Reversible Li–O₂ Battery

Abstract The lithium–oxygen (Li–O₂) battery with high energy density of 3860 Wh kg⁻¹ represents one of the most promising new secondary batteries for future electric vehicles and mobile electronic devices. However, slow oxygen reduction/oxygen evolution (ORR/OER) reaction efficiency and unstable cycling performance restrain the practical applications of the Li–O₂ battery. Herein, Ru‐modified nitrogen‐doped porous carbon‐encapsulated Co nanoparticles (Ru/Co@CoN_x–C) are synthesized through reduction of Ru on metal–organic framework (MOFs) pyrolyzed derivatives strategies. Porous carbon polyhedra provide channels for reactive species and stable structure ensures the cyclic stability of the catalyst; abundant Co–N_x sites and high specific surface area (353 m² g⁻¹) provide more catalytically active sites and deposition sites for reaction products. Theoretical calculations further verify that Ru/Co@CoN_x–C can regulate the growth of Li₂O₂ to improve reversibility of Li–O₂ batteries. Li–O₂ batteries with Ru/Co@CoN_x–C as cathode catalyst achieve small voltage gaps of 1.08 V, exhibit excellent cycle stability (205 cycles), and deliver high discharge specific capacity (17050 mAh g⁻¹). Furthermore, pouch‐type Li–O₂ batteries that maintain stable electrochemical performance output even under conditions of bending deformation and corner cutting are successfully assembled. This study demonstrates Ru/Co@CoN_x–C catalyst's great application potential in Li–O₂ batteries.