Cage‐Like Sodalite‐Type Porous Organic Salts Enabling Luminescent Molecule's Incorporation and Room‐temperature Phosphorescence Induction in Air

Abstract Expression of room‐temperature phosphorescence (RTP) in organic materials requires complicated molecular design and specific intermolecular interactions, and therefore types of RTP materials are restricted. This work presents cage‐like sodalite‐type porous organic salts (s‐POSs) as host materials for luminescent molecules to induce RTP, using tetrasulfonic acid with an adamantane core and triphenylmethylamines that are modified with substituents in the para‐positions of benzene rings (TPMA‐X). By adding a representative luminescent molecule (pyrene) to a reaction solution during construction of s‐POSs, the molecule is incorporated in a facile manner. s‐POSs with a heavy halogen atom (X: Iodine) on the pore surface give heavy atom effects, suppression of thermal vibration, and protection from oxygen, for the incorporated molecule, which induce its RTP even in air. This strategy can be applied to various luminescent molecules, which may lead to the achievement of RTP of various colors.