Pomegranate‐Like KVPO₄F@C Microspheres as High‐Volumetric‐Energy‐Density Cathode for Potassium‐Ion Batteries

Abstract KVPO₄F is one of the most competitive cathode candidates for potassium‐ion batteries (KIBs) because of its high output voltage and energy density. Although the gravimetric energy density of KIBs is intensively discussed in literature, little attention is paid to the volumetric energy density. In view of this, pomegranate‐like carbon‐coated KVPO₄F microspheres with a high volumetric energy density are designed in this work. The nano‐sized primary particles with carbon sheets in KVPO₄F microspheres enable promis rate capability by enhancing the K⁺ diffusion kinetics, while the micro‐sized spheres guarantee the improvement of cycling stability. Owing to the dense hierarchical microspheres, the volumetric energy density of cells is greatly improved compared to bulk materials. This cathode delivers a reversible capacity of 101.5 mA h g⁻¹ at 0.3 C with an average output voltage of 4.0 V and a capacity retention of 85.1% after 200 cycles. The KVPO₄F@C microspheres have a compact density of 2.45 g cm⁻³ and further offer a high volumetric energy density up to 891.3 Wh L⁻¹. The overcharge behavior of KVPO₄F in the first three cycles is also revealed. The presented KVPO₄F@C microspheres cathode provides a new sight for developing KIBs with large volumetric energy density.