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journal article·2023-11

Insights into Reversible Sodium Intercalation in a Novel Sodium‐Deficient NASICON‐Type Structure:Na3.40□0.60Co0.5Fe0.5V(PO4)3

Jingrong Hou, Mohammed Hadouchi, Lijun Sui, Jie Liu, Mingxue Tang, Zhiwei Hu, Hong‐Ji Lin, Chang‐Yang Kuo, Chien‐Te Chen, Chih‐Wen Pao, Yunhui Huang, Jiwei Ma

Small· Volume 19· Issue 46
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Source abstract

Abstract

Abstract The rational design of novel high‐performance cathode materials for sodium‐ion batteries is a challenge for the development of the renewable energy sector. Here, a new sodium‐deficient NASICON phosphate, namely Na3.40□0.60Co0.5Fe0.5V(PO4)3, demonstrating the excellent electrochemical performance is reported. The presence of Co allows a third Na+ to participate in the reaction thus exhibiting a high reversible capacity of ≈155 mAh g−1 in the voltage range of 2.0–4.0 V versus Na+/Na with a reversible single‐phase mechanism and a small volume shrinkage of ≈5.97% at 4.0 V. 23Na solid‐state nuclear magnetic resonance (NMR) combined with ex situ X‐ray diffraction (XRD) refinements provide evidence for a preferential Na+ insertion within the Na2 site. Furthermore, the enhanced sodium kinetics ascribed to Co‐substitution is also confirmed in combination with electrochemical impedance spectroscopy (EIS), galvanostatic intermittent titration technique (GITT), and theoretical calculation.
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Research context

Energy storage

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Chemical Synthesis and Characterization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials Institute of New Energy for Vehicles School of Materials Science and Engineering Tongji University Shanghai 201804 China

Laboratoire de Chimie Appliquée des Matériaux Centre des Sciences des Matériaux Faculty of Science Mohammed V University in Rabat Avenue Ibn Battouta Rabat BP 1014 Morocco

Center for High Pressure Science & Technology Advanced Research Beijing 100094 China

Max Planck Institute for Chemical Physics of Solids Nöthnitzer Strasse 40 01187 Dresden Germany

National Synchrotron Radiation Research Center 101 Hsin‐Ann Road Hsinchu 30076 Taiwan

Department of Electrophysics National Yang Ming Chiao Tung University Hsinchu 30076 Taiwan

Key Laboratory of Material Processing and Die & Mold Technology School of Materials Science and Engineering Huazhong University of Science and Technology Wuhan Hubei 430074 China

Funding

National Natural Science Foundation of China

References (57)

Show source-provided references
1. 10.1021/es403778610.1021/es4037786 ↗
2. 10.1126/science.121274110.1126/science.1212741 ↗
3. 10.1002/bte2.2021001010.1002/bte2.20210010 ↗
4. 10.1002/adfm.20120069110.1002/adfm.201200691 ↗
5. 10.1038/nchem.68010.1038/nchem.680 ↗
6. Pan H. · Environ. Sci. · 2013 · 6 · 2338
7. 10.1002/aenm.20170286910.1002/aenm.201702869 ↗
8. 10.1021/acs.energyfuels.0c0289710.1021/acs.energyfuels.0c02897 ↗
9. 10.1002/aenm.20200205510.1002/aenm.202002055 ↗
10. 10.1002/aenm.20200364010.1002/aenm.202003640 ↗
11. 10.1021/acsenergylett.1c0229210.1021/acsenergylett.1c02292 ↗
12. 10.1002/aenm.20200131010.1002/aenm.202001310 ↗
13. 10.1016/j.ensm.2021.07.04010.1016/j.ensm.2021.07.040 ↗
14. 10.1016/j.ensm.2020.11.01010.1016/j.ensm.2020.11.010 ↗
15. 10.1038/s41467-019-08359-y10.1038/s41467-019-08359-y ↗
16. 10.1038/natrevmats.2018.1310.1038/natrevmats.2018.13 ↗
17. 10.1002/aenm.20170027410.1002/aenm.201700274 ↗
18. Li S. · J. Electrochem. · 2015 · 21 · 332
19. 10.1002/adfm.20200047310.1002/adfm.202000473 ↗
20. 10.1002/aenm.20110077210.1002/aenm.201100772 ↗
21. 10.1002/advs.20160027510.1002/advs.201600275 ↗
22. 10.1002/aenm.20180141810.1002/aenm.201801418 ↗
23. 10.1038/s41560-021-00865-y10.1038/s41560-021-00865-y ↗
24. 10.1002/adma.20170043110.1002/adma.201700431 ↗
25. 10.1039/D3TA00014A10.1039/D3TA00014A ↗
26. 10.1107/S002188986900655810.1107/S0021889869006558 ↗
27. 10.1107/S010876818500206310.1107/S0108768185002063 ↗
28. 10.1103/PhysRevB.77.10444210.1103/PhysRevB.77.104442 ↗
29. 10.1103/PhysRevB.81.11513810.1103/PhysRevB.81.115138 ↗
30. 10.1021/cm202542q10.1021/cm202542q ↗
31. Chang C. F. · Phys. Rev. X · 2016 · 6
32. 10.1103/PhysRevB.100.01444310.1103/PhysRevB.100.014443 ↗
33. 10.1103/PhysRevB.80.08511110.1103/PhysRevB.80.085111 ↗
34. 10.1103/PhysRevB.82.18442910.1103/PhysRevB.82.184429 ↗
35. 10.1103/PhysRevB.55.1550010.1103/PhysRevB.55.15500 ↗
36. 10.1103/PhysRevB.61.1150610.1103/PhysRevB.61.11506 ↗
37. 10.1103/PhysRevB.77.12512410.1103/PhysRevB.77.125124 ↗
38. 10.1103/PhysRevLett.102.11640110.1103/PhysRevLett.102.116401 ↗
39. 10.1039/C5TA10520J10.1039/C5TA10520J ↗
40. 10.1002/adfm.20120158910.1002/adfm.201201589 ↗
41. 10.1016/j.nanoen.2020.10454810.1016/j.nanoen.2020.104548 ↗
42. 10.1002/adma.20130552210.1002/adma.201305522 ↗
43. 10.1149/1.212893910.1149/1.2128939 ↗
44. 10.1021/acs.chemmater.6b0272610.1021/acs.chemmater.6b02726 ↗
45. 10.1002/smll.20170286410.1002/smll.201702864 ↗
46. 10.1002/aenm.20160270610.1002/aenm.201602706 ↗
47. 10.1039/C5TA00765H10.1039/C5TA00765H ↗
48. 10.1021/cr020734p10.1021/cr020734p ↗
49. 10.1021/acs.chemmater.7b0258910.1021/acs.chemmater.7b02589 ↗
50. 10.1016/0921-4526(93)90108-I10.1016/0921-4526(93)90108-I ↗
51. K.Brandenburg H.Putz Crystal Impact GbR Bonn Germany.2006.
52. 10.1002/mrc.98410.1002/mrc.984 ↗
53. 10.1103/PhysRevB.54.1116910.1103/PhysRevB.54.11169 ↗
54. 10.1103/PhysRevB.47.55810.1103/PhysRevB.47.558 ↗
55. 10.1103/PhysRevB.57.150510.1103/PhysRevB.57.1505 ↗
56. 10.1103/PhysRevB.71.03510910.1103/PhysRevB.71.035109 ↗
57. 10.1103/PhysRevB.59.175810.1103/PhysRevB.59.1758 ↗