Switchable Circularly Polarized Signals with High Asymmetric Factor Triggered by Dual Photonic Bandgap Structure

Abstract Currently, the smart photonic materials that can switch circularly polarized signals in real‐time have attracted extensive attention due to numerous potential applications in information storage and photonics displays. However, the dynamically reversible switching of circularly polarized signals requires precise structural reconfiguration, which is rarely achieved in traditional biomaterials. Herein, a dual photonic bandgap (PBG) structure is constructed based on the optical propagation principle of cellulose‐based photonic crystals, enabling the flexible switching of the intensity, wavelength, and direction of circularly polarized luminescence (CPL). By adjusting the fluorescence intensity and the matching degree of chiral structure, the asymmetric factor value of dual PBG structure is up to −1.47, far exceeding other cellulose‐based materials. Importantly, it is demonstrated that dual CPL emission can be efficiently induced by two different PBGs, opening a new approach for on‐demand switching of single and dual CPL emission. In addition, the dual PBG structure exhibits dual circularly polarized reflected signals under the circular polarizer, which perfectly embodies the applicability of multiple encryptions in QR codes. This work provides new insights into the real‐time manipulation of circularly polarized signals by chiral photonic materials.